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    by Bowman-James, Kristin
    Published 2012
    Table of Contents ...Cover; Related Titles; Title Page; Copyright; Preface; List of Contributors; Chapter 1: Aspects of Anion Coordination from Historical Perspectives; 1.1 Introduction; 1.2 Halide and Pseudohalide Anions; 1.3 Oxoanions; 1.4 Phosphate and Polyphosphate Anions; 1.5 Carboxylate Anions and Amino Acids; 1.6 Anionic Complexes: Supercomplex Formation; 1.7 Nucleotides; 1.8 Final Notes; References; Chapter 2: Thermodynamic Aspects of Anion Coordination; 2.1 Introduction; 2.2 Parameters Determining the Stability of Anion Complexes; 2.3 Molecular Recognition and Selectivity. 2.4 Enthalpic and Entropic Contributions in Anion CoordinationReferences; Chapter 3: Structural Aspects of Anion Coordination Chemistry; 3.1 Introduction; 3.2 Basic Concepts of Anion Coordination Chemistry; 3.3 Classes of Anion Hosts; 3.4 Acycles; 3.5 Monocycles; 3.6 Cryptands; 3.7 Transition-Metal-Assisted Ligands; 3.8 Lewis Acid Ligands; 3.9 Conclusion; 3.10 Acknowledgments; References; Chapter 4: Synthetic Strategies; 4.1 Introduction; 4.2 Design and Synthesis of Polyamine-Based Receptors for Anions; 4.3 Design and Synthesis of Amide Receptors; References; Chapter 5: Template Synthesis. 5.1 Introductory Remarks5.2 Macrocyclic Systems; 5.3 Bowl-Shaped Systems; 5.4 Capsule, Cage, and Tube-Shaped Systems; 5.5 Circular Helicates and meso-Helicates; 5.6 Mechanically Linked Systems; 5.7 Concluding Remarks; References; Chapter 6: Anion-p Interactions in Molecular Recognition; 6.1 Introduction; 6.2 Physical Nature of the Interaction; 6.3 Energetic and Geometric Features of the Interaction Depending on the Host (Aromatic Moieties) and the Guest (Anions); 6.4 Influence of Other Noncovalent Interactions on the Anion-p Interaction. 6.5 Experimental Examples of Anion-p Interactions in the Solid State and in Solution6.6 Concluding Remarks; References; Chapter 7: Receptors for Biologically Relevant Anions; 7.1 Introduction; 7.2 Phosphate Receptors; 7.3 Carboxylate Receptors; 7.4 Conclusion; References; Chapter 8: Synthetic Amphiphilic Peptides that Self-Assemble to Membrane-Active Anion Transporters; 8.1 Introduction and Background; 8.2 Biomedical Importance of Chloride Channels; 8.3 The Development of Synthetic Chloride Channels; 8.4 Approaches to Synthetic Chloride Channels. 8.5 The Development of Amphiphilic Peptides as Anion Channels8.6 Structural Variations in the SAT Modular Elements; 8.7 Conclusions; Acknowledgments; References; Chapter 9: Anion Sensing by Fluorescence Quenching or Revival; 9.1 Introduction; 9.2 Anion Recognition by Dynamic and Static Quenching of Fluorescence; 9.3 Fluorescent Sensors Based on Anthracene and on a Polyamine Framework; 9.4 Turning on Fluorescence with the Indicator Displacement Approach; References; Index....
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